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Can smoking ignite gasoline fumes On One Hand: Smoking Can Ignite Gasoline VaporsGasoline and its vapors are highly flammable, but the vapors are especially dangerous. They are heavier than air, spread quickly and can ignite from a small ignition source, such as a cigarette. When you're working with gasoline, it's important to be in a well-ventilated area and not smoke nearby. When you're putting gasoline in your car at a gas station, always be aware that vapors may be present; never smoke or light matches or lighters while refueling. On the Other: Cigarettes Won't Light LiquidIn order for gasoline vapors to catch fire from a cigarette or other ignition source, there must be a particular mix of gasoline and air. According to a Mythbusters test, cigarettes will not ignite gasoline in its liquid form. Bottom LineSmoking around gasoline is dangerous because lit cigarettes can ignite gasoline vapors. Proper gasoline storage, not smoking around gasoline and handling gas outdoors to allow for proper ventilation will help prevent fires.